The following is with reference to Air Pollutants,
(* means multiplication and, / means division)
ppb :- parts per billion by volume
ppm :- parts per million by volume
1 ppb = 0.001 ppm = 10-3 ppm
1% = 10000 ppm
% = ppm * 10-4
% = (103 ppb *10-4) = (ppb/10)
%= ppm * 10-4 = ppb * 10-1
For concentrations (of chemical contaminants or soil contaminants) in water, in soil
the following holds true
1 ppm = (1 mg/Lit, like in water)= (1 mg/Kg, like for concentrations in soil) = (1gm/m3 like for concentration of chemicals in water)
same for ppb,
1 ppb = 1μg/Lit = 1 μg/Kg = mg/m3
But for concentration of air pollutants in Air, following conversion formula is to be used,
mg/m3 is same as mg/Nm3
μg/m3 is same as μg/Nm3
mg/Nm3 = (ppm * MW )/(0.08205 * °K)
where °K is Deg Kelvin and MW is
molecular wt. of air pollutants
At 1 atm pressure and 25°C, the above equation becomes
mg/Nm3 = (ppm* MW)/24.45
or
μg/Nm3 = (ppb* MW)/24.45
Standard molar volume of an ideal gas at 1 atm pressure and 25°C temp = 24.45 m3/mol
and at 0°c this volume is 22.414 m3/mol
(* means multiplication and, / means division)
ppb :- parts per billion by volume
ppm :- parts per million by volume
Numbers
Million = 1,000,000
Billion = 1,000,000,000
Trillion = 1,000,000,000,000
1 ppm = 1000 ppb = 103 ppb1 ppb = 0.001 ppm = 10-3 ppm
1% = 10000 ppm
% = ppm * 10-4
% = (103 ppb *10-4) = (ppb/10)
%= ppm * 10-4 = ppb * 10-1
For concentrations (of chemical contaminants or soil contaminants) in water, in soil
the following holds true
1 ppm = (1 mg/Lit, like in water)= (1 mg/Kg, like for concentrations in soil) = (1gm/m3 like for concentration of chemicals in water)
same for ppb,
1 ppb = 1μg/Lit = 1 μg/Kg = mg/m3
But for concentration of air pollutants in Air, following conversion formula is to be used,
mg/m3 is same as mg/Nm3
μg/m3 is same as μg/Nm3
mg/Nm3 = (ppm * MW )/(0.08205 * °K)
where °K is Deg Kelvin and MW is
molecular wt. of air pollutants
At 1 atm pressure and 25°C, the above equation becomes
mg/Nm3 = (ppm* MW)/24.45
or
μg/Nm3 = (ppb* MW)/24.45
Standard molar volume of an ideal gas at 1 atm pressure and 25°C temp = 24.45 m3/mol
and at 0°c this volume is 22.414 m3/mol
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