Monday, 24 July 2017

Air pollutants Unit Conversion

The following is with reference to Air Pollutants,

(* means multiplication and,  / means division)


ppb :-   parts per billion by volume
ppm :-  parts per million by volume


Numbers
Million = 1,000,000
Billion = 1,000,000,000
Trillion = 1,000,000,000,000
1 ppm = 1000 ppb = 103 ppb
1 ppb = 0.001 ppm = 10-3 ppm
1% = 10000 ppm
% = ppm * 10-4
% = (103 ppb *10-4) = (ppb/10)
 %= ppm * 10-4 = ppb * 10-1

For concentrations  (of chemical contaminants or soil contaminants)  in water, in soil

the following holds true

1 ppm = (1 mg/Lit, like in water)= (1 mg/Kg, like for concentrations in soil) = (1gm/m3  like for concentration of chemicals in water)


same for ppb,


1 ppb = 1μg/Lit  = 1 μg/Kg = mg/m3 


But for concentration of air pollutants in Air, following conversion formula is to be used,


mg/m3  is same as  mg/Nm3

μg/m3  is same as  μg/Nm3

mg/Nm3 = (ppm * MW )/(0.08205 * °K)


where °K is Deg Kelvin and MW is 

molecular wt. of air pollutants

At 1 atm pressure and 25°C, the above equation becomes


mg/Nm3  = (ppm* MW)/24.45


or


μg/Nm3  = (ppb* MW)/24.45


Standard molar volume of an ideal gas at 1 atm pressure and 25°C temp = 24.45 m3/mol


and at 0°c this volume is 22.414 m3/mol

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